----------------------------------------------------------------------------- COACH AL2O3(C) P = 1 atm ----------------------------------------------------------------------------- 2 AL1 +1.5 O2(G)= AL2O3(C) REFERENCES AL1 THERMODATA 07/95 [BANK00A] O2(G) THERMODATA 11/94 [BANK00A] AL2O3(C) THERMODATA 02/90 [BANK00A] T CP° S° (G°-H°298)/T H°T-H°298 DeltaH°f DeltaG°f K <--------- cal/mol*K ---------> <---------- cal/mol ----------> 298.15 ---> AL2O3(C) : solide AL1 : solide O2(G) : gaz 298.15 18.888 12.195 -12.195 0 -400502 -378174 300.00 18.984 12.312 -12.196 35 -400508 -378035 400.00 22.947 18.372 -12.995 2151 -400657 -370513 500.00 25.375 23.778 -14.622 4578 -400589 -362982 600.00 26.883 28.547 -16.554 7196 -400421 -355475 700.00 27.938 32.775 -18.575 9940 -400214 -348000 800.00 28.734 36.559 -20.590 12775 -400006 -340556 900.00 29.362 39.981 -22.558 15681 -399848 -333135 933.00 29.542 41.042 -23.193 16653 -399812 -330689 AL1 ---> solide->liquide, L.trans= 2560.00 cal/mol 933.00 29.542 41.042 -23.193 16653 -404932 -330689 1000.00 29.873 43.102 -24.459 18644 -404793 -325362 1100.00 30.294 45.970 -26.286 21653 -404560 -317430 1200.00 30.642 48.621 -28.038 24700 -404302 -309521 1300.00 30.893 51.085 -29.717 27778 -404025 -301633 1400.00 31.104 53.382 -31.326 30878 -403738 -293768 1500.00 31.332 55.536 -32.869 34000 -403439 -285923 1600.00 31.577 57.565 -34.350 37145 -403127 -278099 1700.00 31.839 59.488 -35.772 40316 -402798 -270294 1800.00 32.118 61.315 -37.141 43513 -402452 -262510 1900.00 32.415 63.060 -38.460 46740 -402086 -254745 2000.00 32.728 64.730 -39.732 49997 -401697 -247001 2100.00 33.059 66.335 -40.961 53286 -401285 -239276 2200.00 33.407 67.881 -42.149 56609 -400848 -231571 2300.00 33.772 69.374 -43.301 59968 -400382 -223887 2327.00 33.873 69.769 -43.606 60881 -400252 -221816 AL2O3(C) ---> solide->liquide, L.trans= 26527.25 cal/mol 2327.00 45.906 81.168 -43.606 87408 -373724 -221816 2400.00 45.906 82.586 -44.770 90760 -372492 -217070 2500.00 45.906 84.460 -46.320 95350 -370811 -210628 2600.00 45.906 86.261 -47.822 99941 -369137 -204254 2700.00 45.906 87.993 -49.278 104531 -367471 -197944 2764.00 45.906 89.069 -50.187 107469 -366408 -193938 AL1 ---> liquide->gaz., L.trans= 69504.48 cal/mol 2764.00 45.906 89.069 -50.187 107469 -505417 -194078 2800.00 45.906 89.663 -50.691 109122 -504632 -190028 2900.00 45.906 91.274 -52.062 113713 -502458 -178831 3000.00 45.906 92.830 -53.396 118303 -500290 -167708 3100.00 45.906 94.335 -54.692 122894 -498130 -156658 3200.00 45.906 95.793 -55.954 127484 -495977 -145677 3300.00 45.906 97.205 -57.183 132075 -493831 -134763 3400.00 45.906 98.576 -58.380 136666 -491692 -123914 3500.00 45.906 99.906 -59.547 141256 -489560 -113128 3600.00 45.906 101.200 -60.687 145847 -487435 -102403 3700.00 45.906 102.457 -61.799 150438 -485315 -91737 3800.00 45.906 103.682 -62.885 155028 -483201 -81128 3900.00 45.906 104.874 -63.946 159619 -481092 -70575 4000.00 45.906 106.036 -64.984 164209 -478989 -60076 4100.00 45.906 107.170 -65.999 168800 -476893 -49629 4200.00 45.906 108.276 -66.993 173391 -474802 -39233 4300.00 45.906 109.356 -67.965 177981 -472717 -28887 4400.00 45.906 110.412 -68.918 182572 -470639 -18589 4500.00 45.906 111.443 -69.852 187162 -468566 -8339 Tmax :AL2O3(C)= 4500.00K